Hi @tim.adams,
The current items in not allowed appear to be illegal character issues with OneDrive for Business, which has really strict rules on allowed characters. In this case it looks to be the “%” character.
For WebDAV, the server is throwing an exception, but it is generic. Can you tell me the name of the file(s) that are not able to sync? There may be an issue with mime typing or special characters that needs to be adjusted on the WebDAV server side. More on that here:
You should be able to find the WebDAV logfiles in C:\inetpub\logs\LogFiles\W3SVC1. These may give us some better info on what is happening too.